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AWWA ACE94141

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AWWA ACE94141 Dehalogenation of Chlorinated Organics by Zero-Valence Metals

Conference Proceeding by American Water Works Association, 01/01/1994

Warren, Kara D.; Arnold, Robert G.; Bishop, Tammie L.; Lindholm,Larson C.; Betterton, Eric A.

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Elemental iron and zinc have been used to reductively convert part-per-thousand levels of aqueous phase carbon tetrachloride to chloroform in a few hours. Free metal ions, chloride ion and hydrogen gas are produced in the reaction, whereas protons are consumed. Process kinetics are dependent on solution pH, surface area of the elemental metal, carbon tetrachloride concentration, buffer selection and type of solvent. Dehalogenation reactions using elemental metals offer promise as a means for initiating the destruction of heavily halogenated organic compounds.

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Published: 01/01/1994 ISBN(s): 0898677742 Number of Pages: 7File Size: 1 file , 230 KB